1. Le Mans - McQueen actually drove a 917 at over 200MPH while filming.
2. Ronin - S8 all wheel drift on cobblestones
3. Goldeneye - DB4 v. F355 on mountain roads. Best sound in a movie of real engines. F355 at WOT = drool.
Honorable Mention
Fazcination - RUF CTR 'Yellow Bird' does the Nurburgring, unbelievable skill. Not really a movie though, more of a documentary.