the main cat vs. secondary?
let me ask you this, is the cat or cats you're going to remove on the exhaust manifold? If so, that's what we call the light-up cats, or pre-cats. If you're planning on gutting those, yes, they will net you some good hp gains.
The main cat is the cat right behind the ypipe and near the flex joint. If you're planning on gutting it, DO NOT. If you're planning on putting a straight piece of pipe in place of the cat, that should work well.
Hope that helps.