Bondo is a two part putty. One is the putty and the other is the hardener. Basically, you just mix a little bit of hardener with the putty and then apply it where you need it. Generally, when your working with it, it needs to be about 60 degrees outside for it to fully harden in about 1-2 hours. When applying it, you'll want to make sure that the area is scuffed up really well with some 400-600 grit sandpaper so it gives the bondo better bonding when it drys and you start sanding.
That being said, Not sure where the crack is on your front bumper, but bondo is very brittle once hardened and is prone to cracking on a flexible surfaces. It might be fine for filling in pits and scratches in a front bumper, but I'd really have to see the spot where its cracked because it may just end up cracking apart again later down the road since the bumper is a flexible polyeurathane.
Where is it cracked?