Rear toe is adjustable, and how they relate to the front is the thrust angle.
This is how I have it done on my car.
Install the front camber kits. Requires pulling down the front struts. Adjust the fronts to a rough adjustment.
Go to the rear and confirm that the camber is livable (not knocked out from collision damage and/or bent parts). Set the rear toe. I like the rear to be as close to 0 as possible while still being slightly toed in. Check the thrust angle, and tinker with balancing the rear toe adjustment to keep the toe where it belongs while bringing the thrust angle to 0. The closer to 0 the better, and with a little attention you can get it to 0.
Then move to the front. To adjust the front caster and camber, you will need to raise the wheel being adjusted. Instructions are with the camber kits.
Determine ahead of time where you want the camber. The closer to 0 the more even the tire wear. The more the negative camber, the better the car handles. You probably want it under .7, although some say they are OK with tire wear with it close to max spec (1.3 IIRC). For me, the 1.3 was way too much. I have mine slightly negative but close to 0.
When you change the camber, the caster will change too. Basically, you have a choice of negative caster or positive caster. With power steering, you don't need negative caster. Negative caster is easier to steer, and positive caster provides better steering wheel returnability after turns. Don't worry about too much positive caster. There isn't enough adjustment to get you into trouble.
On a flat road (they don't exist), if caster and camber are even on both sides with a 0 thrust angle, the car will go straight down the road. Due to road crown, you need a very slight lead on the right wheel. You can do that with a little up to .5 more positive caster or with about .25 more negative camber, or a slight mix of both. You alignment guy should know what to do. If you can't get the cross camber and cross caster (the relationship between right and left side) where it belongs, you may need to shift the subframe.
End up by setting the front toe. The right to left front toe needs to be even. I prefer it to be as close to 0 as possible while still being slightly toed out (the opposite of the rear).
Since all the readings are somewhat related, confirm that all is where it should be before removing the car from the alignment rack.
Road test and confirm that it handles as it should.